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๐ Supramolecular Chemistry
Supramolecular chemistry refers to the branch of chemistry concerning chemical systems composed of a discrete number of molecules. The strength of the forces responsible for spatial organization of the system range from weak intermolecular forces, electrostatic charge, or hydrogen bonding to strong covalent bonding, provided that the electronic coupling strength remains small relative to the energy parameters of the component. While traditional chemistry concentrates on the covalent bond, supramolecular chemistry examines the weaker and reversible non-covalent interactions between molecules. These forces include hydrogen bonding, metal coordination, hydrophobic forces, van der Waals forces, piโpi interactions and electrostatic effects.
Important concepts advanced by supramolecular chemistry include molecular self-assembly, molecular folding, molecular recognition, hostโguest chemistry, mechanically-interlocked molecular architectures, and dynamic covalent chemistry. The study of non-covalent interactions is crucial to understanding many biological processes that rely on these forces for structure and function. Biological systems are often the inspiration for supramolecular research.
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- "Supramolecular Chemistry" | 2023-07-27 | 10 Upvotes 1 Comments
๐ Satanic Panic
The Satanic panic is a moral panic consisting of over 12,000 unsubstantiated cases of Satanic ritual abuse (SRA, sometimes known as ritual abuse, ritualistic abuse, organized abuse, or sadistic ritual abuse) starting in the United States in the 1980s, spreading throughout many parts of the world by the late 1990s, and persisting today. The panic originated in 1980 with the publication of Michelle Remembers, a book co-written by Canadian psychiatrist Lawrence Pazder and his patient (and future wife), Michelle Smith, which used the discredited practice of recovered-memory therapy to make sweeping lurid claims about satanic ritual abuse involving Smith. The allegations, which afterwards arose throughout much of the United States, involved reports of physical and sexual abuse of people in the context of occult or Satanic rituals. In its most extreme form, allegations involve a conspiracy of a global Satanic cult that includes the wealthy and elite in which children are abducted or bred for human sacrifices, pornography, and prostitution.
Nearly every aspect of the ritual abuse is controversial, including its definition, the source of the allegations and proof thereof, testimonies of alleged victims, and court cases involving the allegations and criminal investigations. The panic affected lawyers, therapists, and social workers who handled allegations of child sexual abuse. Allegations initially brought together widely dissimilar groups, including religious fundamentalists, police investigators, child advocates, therapists, and clients in psychotherapy. The term satanic abuse was more common early on; this later became satanic ritual abuse and further secularized into simply ritual abuse. Over time, the accusations became more closely associated with dissociative identity disorder (then called multiple personality disorder) and anti-government conspiracy theories.
Initial interest arose via the publicity campaign for Pazder's 1980 book Michelle Remembers, and it was sustained and popularized throughout the decade by coverage of the McMartin preschool trial. Testimonials, symptom lists, rumors, and techniques to investigate or uncover memories of SRA were disseminated through professional, popular, and religious conferences as well as through talk shows, sustaining and further spreading the moral panic throughout the United States and beyond. In some cases, allegations resulted in criminal trials with varying results; after seven years in court, the McMartin trial resulted in no convictions for any of the accused, while other cases resulted in lengthy sentences, some of which were later reversed. Scholarly interest in the topic slowly built, eventually resulting in the conclusion that the phenomenon was a moral panic, which, as one researcher put it in 2017, "involved hundreds of accusations that devil-worshipping paedophiles were operating America's white middle-class suburban daycare centers."
Of the more than 12,000 documented accusations nationwide, investigating police were not able to substantiate any allegations of organized cult abuse.
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- "Satanic Panic" | 2023-07-27 | 22 Upvotes 20 Comments
๐ Hobby Tunneling
Hobby tunneling (or tunnelling) is tunnel construction as a diversion. Usually, hobby tunnelers dig their tunnels by hand, using little equipment, and some can spend years or even decades to achieve any degree of completion. In some cases tunnels have been dug secretly, and only discovered by chance.
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- "Hobby Tunneling" | 2023-07-26 | 23 Upvotes 13 Comments
- "Hobby Tunneling" | 2021-08-21 | 22 Upvotes 6 Comments
๐ Hello
Hello is a salutation or greeting in the English language. It is first attested in writing from 1826.
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- "Hello" | 2023-07-26 | 25 Upvotes 7 Comments
๐ Padmanabhaswamy Temple Treasure
The Padmanabhaswamy temple treasure is a collection of valuable objects including gold thrones, crowns, coins, statues and ornaments, diamonds and other precious stones. It was discovered in some of the subterranean vaults of the Padmanabhaswamy Temple in Thiruvananthapuram, in the Indian state of Kerala, when five of its six (or possibly eight) vaults were opened on 27 June 2011. The vaults were opened on the orders of the Supreme Court of India, which was hearing a private petition seeking transparency in the running of the temple. The discovery of the treasure attracted widespread national and international media attention as it is considered to be the largest collection of items of gold and precious stones in the recorded history of the world. On the possibility of future appropriation of the wealth, for the need of a new management and proper inventorisation of the articles in the vaults, a public interest petition was registered with Supreme court of India. In 2020, the royal family won the rights to manage the temple, as well all its financial aspects. The Supreme Court of India overruled the Kerala High Court's legal jurisprudence based on regional facts and recognition of the nullified princely agreement based on "Ruler of Travancore."
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- "Padmanabhaswamy Temple Treasure" | 2023-07-26 | 26 Upvotes 3 Comments
๐ Suwaลki Gap
The Suwaลki Gap, also known as the Suwaลki corridor ([suหvawkสฒi] (listen)), is a sparsely populated area immediately southwest of the border between Lithuania and Poland, between Belarus and the Russian exclave of Kaliningrad Oblast. Named after the Polish town of Suwaลki, this choke point has become of great strategic and military importance since Poland and the Baltic states joined the North Atlantic Treaty Organization (NATO).
The border between Poland and Lithuania was formed after the Suwaลki Agreement of 1920; but it carried little importance in the interwar period as at the time, the Polish lands stretched farther northeast, while during the Cold War, Lithuania was part of the Soviet Union and communist Poland belonged to the Soviet-led Warsaw Pact alliance. The dissolution of the Soviet Union and the Warsaw Pact created borders that cut through the shortest land route between Kaliningrad (Russian territory isolated from the mainland) and Belarus (Russia's ally). As the Baltic states and Poland eventually joined NATO, this narrow border stretch between Poland and Lithuania became a vulnerability for the military bloc because, if a hypothetical military conflict were to erupt between Russia and Belarus on one side and NATO on the other, the capture of the 65ย km (40ย mi)-long strip of land between Russia's Kaliningrad Oblast and Belarus would likely jeopardise NATO's attempts to defend the Baltic states. NATO's fears about the Suwaลki Gap intensified after 2014, when Russia annexed Crimea and launched the war in Donbas, and further increased after Russia invaded Ukraine in February 2022. These worries prompted the alliance to increase its military presence in the area, and an arms race was triggered by these events.
Both Russia and the European Union countries also saw great interest in civilian uses of the gap. In the 1990s and early 2000s, Russia attempted to negotiate an extraterritorial corridor to connect its exclave of Kaliningrad Oblast with Grodno in Belarus, but Poland, Lithuania and the EU did not consent. Movement of goods through the gap was disrupted in summer 2022, during the Russian invasion of Ukraine, as Lithuania and the European Union introduced transit restrictions on Russian vehicles as part of their sanctions. The Via Baltica road, a vital link connecting Finland and the Baltic states with the rest of the European Union, goes through the area and, as of November 2022, is under construction in Poland as expressway S61.
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- "Suwaลki Gap" | 2023-07-25 | 28 Upvotes 15 Comments
๐ Logo of the X Window System ca. 1990?
The X Window System (X11, or simply X) is a windowing system for bitmap displays, common on Unix-like operating systems.
X provides the basic framework for a GUI environment: drawing and moving windows on the display device and interacting with a mouse and keyboard. X does not mandate the user interfaceย โ this is handled by individual programs. As such, the visual styling of X-based environments varies greatly; different programs may present radically different interfaces.
X originated as part of Project Athena at Massachusetts Institute of Technology (MIT) in 1984. The X protocol has been at version 11 (hence "X11") since September 1987. The X.Org Foundation leads the X project, with the current reference implementation, X.Org Server, available as free and open-source software under the MIT License and similar permissive licenses.
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- "Logo of the X Window System ca. 1990?" | 2023-07-24 | 12 Upvotes 2 Comments
๐ Hallucinogenic Plants in Chinese Herbals
For over two millennia, texts in Chinese herbology and traditional Chinese medicine have recorded medicinal plants that are also hallucinogens and psychedelics. Some are familiar psychoactive plants in Western herbal medicine (e.g., Chinese: ่จ่ช; pinyin: lร ngdร ng, i.e. Hyoscyamus niger), but several Chinese plants have not been noted as hallucinogens in modern works (e.g.,Chinese: ้ฒๅฏฆ; pinyin: yรบnshรญ; lit. 'cloud seed', i.e. Caesalpinia decapetala). Chinese herbals are an important resource for the history of botany, for instance, Zhang Hua's c. 290 Bowuzhi is the earliest record of the psilocybin mushroom xiร ojรนn ็ฌ่ (lit. "laughing mushroom", i.e. Gymnopilus junonius).
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- "Hallucinogenic Plants in Chinese Herbals" | 2023-07-24 | 49 Upvotes 6 Comments
๐ Bidet Shower โ Hand Bidet, Commode/Toilet/Bum Shower, Health Faucet, Bum Gun
A bidet showerโalso known as a handheld bidet, commode shower, toilet shower, health faucet, bum shower, shatafa (from the Arabic: ุดูุทููุงููุฉ [สษtหคหtหคษหfษ], "rinser") or bum gunโis a hand-held triggered nozzle that is placed near the toilet and delivers a spray of water used for anal cleansing and cleaning of the genitals after using the toilet for defecation and urination, popularised by Arab nations where the bidet shower is a common bathroom accessory. The device is similar to that of a kitchen sink sprayer.
In predominantly Catholic countries, the Muslim world, in the Eastern Orthodox and Hindu cultures, and in some Protestant countries such as Finland, water is usually used for anal cleansing, using a jet (bidet shower, bidet) or vessel, and a person's hand (in some places only the left hand is used).
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- "Bidet Shower โ Hand Bidet, Commode/Toilet/Bum Shower, Health Faucet, Bum Gun" | 2023-07-24 | 22 Upvotes 24 Comments
๐ Crop Milk
Crop milk is a secretion from the lining of the crop of parent birds in some species that is regurgitated to young birds. It is found among all pigeons and doves where it is also referred to as pigeon milk. Crop milk is also secreted from the crop of flamingos and the male emperor penguin, suggesting independent evolution of this trait. Unlike in mammals where only females produce milk, crop milk is produced by both males and females in pigeons and flamingos; and in penguins, only by the male. Lactation in birds is controlled by prolactin, which is the same hormone that causes lactation in mammals. Crop milk is a holocrine secretion, unlike in mammals where milk is an exocrine secretion. Crop milk contains both fat and protein, as with mammalian milk, but unlike mammalian milk, it contains no carbohydrates.
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- "Crop Milk" | 2023-07-23 | 25 Upvotes 4 Comments