Topic: Chemistry (Page 3)

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πŸ”— Alcohol Powder

πŸ”— Food and drink πŸ”— Chemistry

Alcohol powder or powdered alcohol or dry alcohol is a product generally made using micro-encapsulation. When reconstituted with water, alcohol (specifically ethanol) in powder form becomes an alcoholic drink. In March 2015 four product labels for specific powdered alcohol products were approved by the United States Alcohol and Tobacco Tax and Trade Bureau (TTB) which opened the doors for legal product sales. However, as of 4 January 2016, the product is not yet available for sale and legalization remains controversial due to public-health and other concerns. Researchers have expressed concern that, should the product go into production, increases in alcohol misuse, abuse, and associated physical harm to its consumers could occur above what has been historically associated with liquid alcohol alone.

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πŸ”— Bacteria in clouds

πŸ”— Climate change πŸ”— Meteorology πŸ”— Chemistry

In meteorology, a cloud is an aerosol consisting of a visible mass of minute liquid droplets, frozen crystals, or other particles suspended in the atmosphere of a planetary body or similar space. Water or various other chemicals may compose the droplets and crystals. On Earth, clouds are formed as a result of saturation of the air when it is cooled to its dew point, or when it gains sufficient moisture (usually in the form of water vapor) from an adjacent source to raise the dew point to the ambient temperature.

They are seen in the Earth's homosphere (which includes the troposphere, stratosphere, and mesosphere). Nephology is the science of clouds, which is undertaken in the cloud physics branch of meteorology.

The two methods of naming clouds in their respective layers of the atmosphere are Latin and common. Cloud types in the troposphere, the atmospheric layer closest to Earth's surface, have Latin names due to the universal adoption of Luke Howard's nomenclature. Formally proposed in 1802, it became the basis of a modern international system that divides clouds into five physical forms that appear in any or all of three altitude levels (formerly known as Γ©tages). These physical types, in approximate ascending order of convective activity, include stratiform sheets, cirriform wisps and patches, stratocumuliform layers (mainly structured as rolls, ripples, and patches), cumuliform heaps, and very large cumulonimbiform heaps that often show complex structures. The physical forms are divided by altitude level into 10 basic genus-types.

The Latin names for applicable high-level genera in the troposphere carry a cirro- prefix, and an alto- prefix is added to the names of the mid-level genus-types. Clouds with sufficient vertical extent to occupy more than one altitude level are officially classified as low- or mid-level according to the altitude range at which each initially forms. However they are also more informally classified as multi-level or vertical, which along with low level clouds, do not carry any altitude related prefixes. Most of the genera can be subdivided into species and further subdivided into varieties. Very low stratiform clouds that extend down to the Earth's surface are given the common names fog and mist, but have no Latin names.

Several cloud types that form higher up in the stratosphere and mesosphere have common names for their main types, which may have the appearance of stratiform sheets, cirriform wisps, or statocumuliform bands or ripples. They are seen infrequently, mostly in the polar regions of Earth. Clouds have been observed in the atmospheres of other planets and moons in the Solar System and beyond. However, due to their different temperature characteristics, they are often composed of other substances such as methane, ammonia, and sulfuric acid, as well as water.

The tabular overview that follows is very broad in scope. It draws from several methods of cloud classification, both formal and informal, used in different levels of the Earth's homosphere by a number of cited authorities. Despite some differences in methodologies and terminologies, the classification schemes seen in this article can be harmonized by using a cross-classifation of form and level to derive the 10 tropospheric genera, the fog and mist that forms at surface level, and several additional major types above the troposphere. The cumulus genus includes four species that indicate vertical size and structure. This table should therefore not be seen as a strict or singular classification, but as an illustration of how various major cloud types are related to each other and defined through a full range of altitude levels from Earth's surface to the "edge of space".

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πŸ”— Bioluminescence

πŸ”— Chemistry πŸ”— Animals πŸ”— Molecular Biology/Molecular and Cell Biology

Bioluminescence is the production and emission of light by living organisms. It is a form of chemiluminescence. Bioluminescence occurs widely in marine vertebrates and invertebrates, as well as in some fungi, microorganisms including some bioluminescent bacteria, and terrestrial arthropods such as fireflies. In some animals, the light is bacteriogenic, produced by symbiotic bacteria such as those from the genus Vibrio; in others, it is autogenic, produced by the animals themselves.

In a general sense, the principal chemical reaction in bioluminescence involves a light-emitting molecule and an enzyme, generally called luciferin and luciferase, respectively. Because these are generic names, luciferins and luciferases are often distinguished by the species or group, e.g. firefly luciferin. In all characterized cases, the enzyme catalyzes the oxidation of the luciferin.

In some species, the luciferase requires other cofactors, such as calcium or magnesium ions, and sometimes also the energy-carrying molecule adenosine triphosphate (ATP). In evolution, luciferins vary little: one in particular, coelenterazine, is found in 11 different animal phyla, though in some of these, the animals obtain it through their diet. Conversely, luciferases vary widely between different species, which is evidence that bioluminescence has arisen over 40 times in evolutionary history.

Both Aristotle and Pliny the Elder mentioned that damp wood sometimes gives off a glow. Many centuries later Robert Boyle showed that oxygen was involved in the process, in both wood and glowworms. It was not until the late nineteenth century that bioluminescence was properly investigated. The phenomenon is widely distributed among animal groups, especially in marine environments. On land it occurs in fungi, bacteria and some groups of invertebrates, including insects.

The uses of bioluminescence by animals include counterillumination camouflage, mimicry of other animals, for example to lure prey, and signaling to other individuals of the same species, such as to attract mates. In the laboratory, luciferase-based systems are used in genetic engineering and biomedical research. Researchers are also investigating the possibility of using bioluminescent systems for street and decorative lighting, and a bioluminescent plant has been created.

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πŸ”— Superionic Water

πŸ”— Physics πŸ”— Astronomy πŸ”— Chemistry πŸ”— Water πŸ”— Astronomy/Solar System

Superionic water, also called superionic ice or ice XVIII, is a phase of water that exists at extremely high temperatures and pressures. In superionic water, water molecules break apart and the oxygen ions crystallize into an evenly spaced lattice while the hydrogen ions float around freely within the oxygen lattice. The freely mobile hydrogen ions make superionic water almost as conductive as typical metals, making it a superionic conductor. It is one of the 19 known crystalline phases of ice. Superionic water is distinct from ionic water, which is a hypothetical liquid state characterized by a disordered soup of hydrogen and oxygen ions.

While theorized for decades, it was not until the 1990s that the first experimental evidence emerged for superionic water. Initial evidence came from optical measurements of laser-heated water in a diamond anvil cell, and from optical measurements of water shocked by extremely powerful lasers. The first definitive evidence for the crystal structure of the oxygen lattice in superionic water came from x-ray measurements on laser-shocked water which were reported in 2019.

If it were present on the surface of the Earth, superionic ice would rapidly decompress. In May 2019, scientists at the Lawrence Livermore National Laboratory (LLNL) were able to synthesize superionic ice, confirming it to be almost four times as dense as normal ice and black in color.

Superionic water is theorized to be present in the mantles of giant planets such as Uranus and Neptune.

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πŸ”— Vantablack

πŸ”— Technology πŸ”— Physics πŸ”— Color πŸ”— Chemistry πŸ”— Science

Vantablack is a material developed by Surrey NanoSystems in the United Kingdom and is one of the darkest substances known, absorbing up to 99.965% of visible light (at 663 nm if the light is perpendicular to the material).

The name is a compound of the acronym VANTA (vertically aligned nanotube arrays) and the color black.

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πŸ”— Olestra

πŸ”— Medicine πŸ”— Food and drink πŸ”— Chemistry πŸ”— Medicine/Toxicology

Olestra (also known by its brand name Olean) is a fat substitute that adds no calories to products. It has been used in the preparation of otherwise high-fat foods, thereby lowering or eliminating their fat content. The Food and Drug Administration (FDA) originally approved olestra for use in the US as a replacement for fats and oils in prepackaged ready-to-eat snacks in 1996, concluding that such use "meets the safety standard for food additives, reasonable certainty of no harm".:β€Š46399β€Š In the late 2000s, olestra lost its popularity due to supposed side effects and has been largely phased out, but products containing the ingredient can still be purchased at grocery stores in some countries. As of 2023, no products are sold in the United States using Olestra.

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πŸ”— Supramolecular Chemistry

πŸ”— Chemistry

Supramolecular chemistry refers to the branch of chemistry concerning chemical systems composed of a discrete number of molecules. The strength of the forces responsible for spatial organization of the system range from weak intermolecular forces, electrostatic charge, or hydrogen bonding to strong covalent bonding, provided that the electronic coupling strength remains small relative to the energy parameters of the component. While traditional chemistry concentrates on the covalent bond, supramolecular chemistry examines the weaker and reversible non-covalent interactions between molecules. These forces include hydrogen bonding, metal coordination, hydrophobic forces, van der Waals forces, pi–pi interactions and electrostatic effects.

Important concepts advanced by supramolecular chemistry include molecular self-assembly, molecular folding, molecular recognition, host–guest chemistry, mechanically-interlocked molecular architectures, and dynamic covalent chemistry. The study of non-covalent interactions is crucial to understanding many biological processes that rely on these forces for structure and function. Biological systems are often the inspiration for supramolecular research.

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πŸ”— Retrobright

πŸ”— Chemistry πŸ”— Polymers

Retrobright refers to H2O2 (hydrogen peroxide) based processes used to remove yellowing from ABS plastics. The usage has also expanded to other retro restoration applications, such as classic and collectible sneaker restoration, where it is referred to by collectors as "sole sauce".

Yellowing in ABS plastic occurs when it is exposed to UV light or excessive heat, which causes photo-oxidation of polymers that breaks polymer chains and causes the plastic to yellow and become brittle.

One method of reversing the yellowed discoloration coined the term (stylized as retr0bright or Retrobrite) was first discovered in 2007 in a German retrocomputing forum, before spreading to an English blog where it was further detailed. The process has been continually refined since.

The long-term effectiveness of these techniques is questioned. Some have discovered the yellowing reappears, and there are concerns that the process weakens and only bleaches the already damaged plastic.