Topic: Chemistry (Page 2)

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๐Ÿ”— Quasicrystals

๐Ÿ”— Physics ๐Ÿ”— Chemistry ๐Ÿ”— Geology ๐Ÿ”— Rocks and minerals

A quasiperiodic crystal, or quasicrystal, is a structure that is ordered but not periodic. A quasicrystalline pattern can continuously fill all available space, but it lacks translational symmetry. While crystals, according to the classical crystallographic restriction theorem, can possess only two-, three-, four-, and six-fold rotational symmetries, the Bragg diffraction pattern of quasicrystals shows sharp peaks with other symmetry ordersโ€”for instance, five-fold.

Aperiodic tilings were discovered by mathematicians in the early 1960s, and, some twenty years later, they were found to apply to the study of natural quasicrystals. The discovery of these aperiodic forms in nature has produced a paradigm shift in the fields of crystallography. Quasicrystals had been investigated and observed earlier, but, until the 1980s, they were disregarded in favor of the prevailing views about the atomic structure of matter. In 2009, after a dedicated search, a mineralogical finding, icosahedrite, offered evidence for the existence of natural quasicrystals.

Roughly, an ordering is non-periodic if it lacks translational symmetry, which means that a shifted copy will never match exactly with its original. The more precise mathematical definition is that there is never translational symmetry in more than nย โ€“ย 1 linearly independent directions, where n is the dimension of the space filled, e.g., the three-dimensional tiling displayed in a quasicrystal may have translational symmetry in two directions. Symmetrical diffraction patterns result from the existence of an indefinitely large number of elements with a regular spacing, a property loosely described as long-range order. Experimentally, the aperiodicity is revealed in the unusual symmetry of the diffraction pattern, that is, symmetry of orders other than two, three, four, or six. In 1982 materials scientist Dan Shechtman observed that certain aluminium-manganese alloys produced the unusual diffractograms which today are seen as revelatory of quasicrystal structures. Due to fear of the scientific community's reaction, it took him two years to publish the results for which he was awarded the Nobel Prize in Chemistry in 2011. On 25 October 2018, Luca Bindi and Paul Steinhardt were awarded the Aspen Institute 2018 Prize for collaboration and scientific research between Italy and the United States.

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๐Ÿ”— Lignum Nephriticum

๐Ÿ”— Chemistry ๐Ÿ”— Plants

Lignum nephriticum (Latin for "kidney wood") is a traditional diuretic that was derived from the wood of two tree species, the narra (Pterocarpus indicus) and the Mexican kidneywood (Eysenhardtia polystachya). The wood is capable of turning the color of water it comes in contact with into beautiful opalescent hues that change depending on light and angle, the earliest known record of the phenomenon of fluorescence. Due to this strange property, it became well known in Europe from the 16th to the early 18th-century. Cups made from lignum nephriticum were given as gifts to royalty. Water drunk from such cups, as well as imported powders and extracts from lignum nephriticum, were thought to have great medicinal properties.

The lignum nephriticum derived from Mexican kidneywood was known as the coatli, coatl, or cuatl ("snake water") or tlapalezpatli ("blood-tincture medicine") in the Nahuatl language. It was traditionally used by the Aztec people as a diuretic prior to European contact. Similarly, the lignum nephriticum cups made from narra wood were part of the native industry of the Philippines before the arrival of the Spanish. The cups were manufactured in southern Luzon, particularly in the Naga region. The name of which was derived from the abundance of the narra trees, which was known as naga in the Bikol language (literally "serpent" or "dragon").

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๐Ÿ”— Conjugate Acids and Bases

๐Ÿ”— Chemistry

A conjugate acid, within the Brรธnstedโ€“Lowry acidโ€“base theory, is a chemical compound formed when an acid donates a proton (H+) to a baseโ€”in other words, it is a base with a hydrogen ion added to it, as in the reverse reaction it loses a hydrogen ion. On the other hand, a conjugate base is what is left over after an acid has donated a proton during a chemical reaction. Hence, a conjugate base is a species formed by the removal of a proton from an acid, as in the reverse reaction it is able to gain a hydrogen ion. Because some acids are capable of releasing multiple protons, the conjugate base of an acid may itself be acidic.

In summary, this can be represented as the following chemical reaction:

Johannes Nicolaus Brรธnsted and Martin Lowry introduced the Brรธnstedโ€“Lowry theory, which proposed that any compound that can transfer a proton to any other compound is an acid, and the compound that accepts the proton is a base. A proton is a nuclear particle with a unit positive electrical charge; it is represented by the symbol H+ because it constitutes the nucleus of a hydrogen atom, that is, a hydrogen cation.

A cation can be a conjugate acid, and an anion can be a conjugate base, depending on which substance is involved and which acidโ€“base theory is the viewpoint. The simplest anion which can be a conjugate base is the solvated electron whose conjugate acid is the atomic hydrogen.

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๐Ÿ”— FOGBANK

๐Ÿ”— Military history ๐Ÿ”— Military history/North American military history ๐Ÿ”— Military history/United States military history ๐Ÿ”— Military history/Military science, technology, and theory ๐Ÿ”— Military history/Weaponry ๐Ÿ”— Physics ๐Ÿ”— Chemistry

FOGBANK is a code name given to a material used in nuclear weapons such as the W76, W78 and W80.

FOGBANK's precise nature is classified; in the words of former Oak Ridge general manager Dennis Ruddy, "The material is classified. Its composition is classified. Its use in the weapon is classified, and the process itself is classified." Department of Energy Nuclear Explosive Safety documents simply describe it as a material "used in nuclear weapons and nuclear explosives" along with lithium hydride (LiH) and lithium deuteride (LiD), beryllium (Be), uranium hydride (UH3), and plutonium hydride.

However National Nuclear Security Administration (NNSA) Administrator Tom D'Agostino disclosed the role of FOGBANK in the weapon: "There's another material in theโ€”it's called interstage material, also known as fog bank", and arms experts believe that FOGBANK is an aerogel material which acts as an interstage material in a nuclear warhead; i.e., a material designed to become a superheated plasma following the detonation of the weapon's fission stage, the plasma then triggering the fusion-stage detonation.

๐Ÿ”— Maillard reaction

๐Ÿ”— Food and drink ๐Ÿ”— Chemistry

The Maillard reaction ( my-YAR; French:ย [majaส]) is a chemical reaction between amino acids and reducing sugars that gives browned food its distinctive flavor. Seared steaks, fried dumplings, cookies and other kinds of biscuits, breads, toasted marshmallows, and many other foods undergo this reaction. It is named after French chemist Louis-Camille Maillard, who first described it in 1912 while attempting to reproduce biological protein synthesis.

The reaction is a form of non-enzymatic browning which typically proceeds rapidly from around 140 to 165ย ยฐC (280 to 330ย ยฐF). Many recipes call for an oven temperature high enough to ensure that a Maillard reaction occurs. At higher temperatures, caramelization (the browning of sugars, a distinct process) and subsequently pyrolysis (final breakdown leading to burning) become more pronounced.

The reactive carbonyl group of the sugar reacts with the nucleophilic amino group of the amino acid, and forms a complex mixture of poorly characterized molecules responsible for a range of aromas and flavors. This process is accelerated in an alkaline environment (e.g., lye applied to darken pretzels; see lye roll), as the amino groups (RNH3+ โ†’ RNH2) are deprotonated, and hence have an increased nucleophilicity. This reaction is the basis for many of the flavoring industry's recipes. At high temperatures, a probable carcinogen called acrylamide can form. This can be discouraged by heating at a lower temperature, adding asparaginase, or injecting carbon dioxide.

In the cooking process, Maillard reactions can produce hundreds of different flavor compounds depending on the chemical constituents in the food, the temperature, the cooking time, and the presence of air. These compounds, in turn, often break down to form yet more new flavor compounds. Flavor scientists have used the Maillard reaction over the years to make artificial flavors.

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๐Ÿ”— PiHKAL: โ€œPhenethylamines I Have Known and Lovedโ€

๐Ÿ”— Books ๐Ÿ”— Alternative Views ๐Ÿ”— Chemistry ๐Ÿ”— Psychoactive and Recreational Drugs

PiHKAL: A Chemical Love Story is a book by Dr. Alexander Shulgin and Ann Shulgin, published in 1991. The subject of the work is psychoactive phenethylamine chemical derivatives, notably those that act as psychedelics and/or empathogen-entactogens. The main title, PiHKAL, is an acronym that stands for "Phenethylamines I Have Known and Loved".

The book is arranged into two parts, the first part being a fictionalized autobiography of the couple and the second part describing 179 different psychedelic compounds (most of which Shulgin discovered himself), including detailed synthesis instructions, bioassays, dosages, and other commentary.

The second part was made freely available by Shulgin on Erowid while the first part is available only in the printed text. While the reactions described are beyond the ability of people with a basic chemistry education, some tend to emphasize techniques that do not require difficult-to-obtain chemicals. Notable among these are the use of mercury-aluminum amalgam (an unusual but easy to obtain reagent) as a reducing agent and detailed suggestions on legal plant sources of important drug precursors such as safrole.

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๐Ÿ”— Island of Stability

๐Ÿ”— Physics ๐Ÿ”— Elements ๐Ÿ”— Elements/Isotope ๐Ÿ”— Chemistry

In nuclear physics, the island of stability is a predicted set of isotopes of superheavy elements that may have considerably longer half-lives than known isotopes of these elements. It is predicted to appear as an "island" in the chart of nuclides, separated from known stable and long-lived primordial radionuclides. Its theoretical existence is attributed to stabilizing effects of predicted "magic numbers" of protons and neutrons in the superheavy mass region.

Several predictions have been made regarding the exact location of the island of stability, though it is generally thought to center near copernicium and flerovium isotopes in the vicinity of the predicted closed neutron shell at Nย =ย 184. These models strongly suggest that the closed shell will confer further stability towards fission and alpha decay. While these effects are expected to be greatest near atomic number Zย =ย 114 and Nย =ย 184, the region of increased stability is expected to encompass several neighboring elements, and there may also be additional islands of stability around heavier nuclei that are doubly magic (having magic numbers of both protons and neutrons). Estimates of the stability of the elements on the island are usually around a half-life of minutes or days; some estimates predict half-lives of millions of years.

Although the nuclear shell model predicting magic numbers has existed since the 1940s, the existence of long-lived superheavy nuclides has not been definitively demonstrated. Like the rest of the superheavy elements, the nuclides on the island of stability have never been found in nature; thus, they must be created artificially in a nuclear reaction to be studied. Scientists have not found a way to carry out such a reaction, for it is likely that new types of reactions will be needed to populate nuclei near the center of the island. Nevertheless, the successful synthesis of superheavy elements up to Zย =ย 118 (oganesson) with up to 177 neutrons demonstrates a slight stabilizing effect around elements 110 to 114 that may continue in unknown isotopes, supporting the existence of the island of stability.

๐Ÿ”— DNA Computing

๐Ÿ”— Computing ๐Ÿ”— Computer science ๐Ÿ”— Biology ๐Ÿ”— Chemistry ๐Ÿ”— Genetics

DNA computing is a branch of computing which uses DNA, biochemistry, and molecular biology hardware, instead of the traditional silicon-based computer technologies. Research and development in this area concerns theory, experiments, and applications of DNA computing. The term "molectronics" has sometimes been used, but this term has already been used for an earlier technology, a then-unsuccessful rival of the first integrated circuits; this term has also been used more generally, for molecular-scale electronic technology.

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๐Ÿ”— You don't know ice. Neither do I, apparently

๐Ÿ”— Physics ๐Ÿ”— Meteorology ๐Ÿ”— Chemistry ๐Ÿ”— Geology ๐Ÿ”— Limnology and Oceanography ๐Ÿ”— Materials

Ice is water frozen into a solid state. Depending on the presence of impurities such as particles of soil or bubbles of air, it can appear transparent or a more or less opaque bluish-white color.

In the Solar System, ice is abundant and occurs naturally from as close to the Sun as Mercury to as far away as the Oort cloud objects. Beyond the Solar System, it occurs as interstellar ice. It is abundant on Earth's surfaceย โ€“ particularly in the polar regions and above the snow lineย โ€“ and, as a common form of precipitation and deposition, plays a key role in Earth's water cycle and climate. It falls as snowflakes and hail or occurs as frost, icicles or ice spikes.

Ice molecules can exhibit eighteen or more different phases (packing geometries) that depend on temperature and pressure. When water is cooled rapidly (quenching), up to three different types of amorphous ice can form depending on the history of its pressure and temperature. When cooled slowly correlated proton tunneling occurs below โˆ’253.15ย ยฐC (20ย K, โˆ’423.67ย ยฐF) giving rise to macroscopic quantum phenomena. Virtually all the ice on Earth's surface and in its atmosphere is of a hexagonal crystalline structure denoted as ice Ih (spoken as "ice one h") with minute traces of cubic ice denoted as ice Ic. The most common phase transition to ice Ih occurs when liquid water is cooled below 0ย ยฐC (273.15ย K, 32ย ยฐF) at standard atmospheric pressure. It may also be deposited directly by water vapor, as happens in the formation of frost. The transition from ice to water is melting and from ice directly to water vapor is sublimation.

Ice is used in a variety of ways, including cooling, winter sports and ice sculpture.

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๐Ÿ”— Alcohol Powder

๐Ÿ”— Food and drink ๐Ÿ”— Chemistry

Alcohol powder or powdered alcohol or dry alcohol is a product generally made using micro-encapsulation. When reconstituted with water, alcohol (specifically ethanol) in powder form becomes an alcoholic drink. In March 2015 four product labels for specific powdered alcohol products were approved by the United States Alcohol and Tobacco Tax and Trade Bureau (TTB) which opened the doors for legal product sales. However, as of 4 January 2016, the product is not yet available for sale and legalization remains controversial due to public-health and other concerns. Researchers have expressed concern that, should the product go into production, increases in alcohol misuse, abuse, and associated physical harm to its consumers could occur above what has been historically associated with liquid alcohol alone.

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